But his wife Keely Shaye Smith had other ideas, turning heads in Leicester Square with a plunging empire line print dress that showed off her voluptuous figure.
Thousands of fans turned out to see Brosnan, 55, arrive along with co-stars Meryl Streep, Julie Walters and Colin Firth.
Pierce Brosnan and wife Keely Shaye Smith arrive for the world premiere of Mamma Mia! at the Odeon West End Cinema Leicester Square in London
Mamma Mia! is a musical based around the hit songs of Seventies band Abba. It follows a teenage girl's quest to find her real father before she gets married.
She writes to the three men who could be her father asking them to the Greek island where the wedding is taking place.
Her potential fathers are played by Brosnan, Firth and Stellan Skarsgard.
Meryl Streep plays the taverna-owning mother Donna and the girl, Sophie, is played by Mean Girls star Amanda Seyfried.
Brosnan married former journalist Miss Shaye Smith, 44, in 2001 and has two sons with her, Dylan and Paris.
Despite all the attention, Keely only has eyes for Pierce
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